Search results for "ring opening reaction"

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Low-temperature molecular layer deposition using monifunctional aromatic precursors and ozone-based ring-opening reactions

2017

Molecular layer deposition (MLD) is an increasingly used deposition technique for producing thin coatings consisting of purely organic or hybrid inorganic-organic materials. When organic materials are prepared, low deposition temperatures are often required to avoid decomposition, thus causing problems with low vapor pressure precursors. Monofunctional compounds have higher vapor pressures than traditional bi- or trifunctional MLD precursors, but do not offer the required functional groups for continuing the MLD growth in subsequent deposition cycles. In this study, we have used high vapor pressure monofunctional aromatic precursors in combination with ozone-triggered ring-opening reactions…

Vapor pressureHydrostatic pressure02 engineering and technologyphenols01 natural sciencesdepositionchemistry.chemical_compoundhybrid materialsElectrochemistryGeneral Materials Sciencecharacterizationinfrared spectroscopyta116Spectroscopyring opening reactionTrifluoromethylvapor pressurehybrid organic-inorganiclow-temperatureSurfaces and Interfacesself assembly021001 nanoscience & nanotechnologyCondensed Matter Physicsdecay (organic)hydrostatic pressure0210 nano-technologyHybrid materialLayer (electronics)Inorganic chemistryta221mechanismnegative ions010402 general chemistrycomplex mixturesinorganic coatingsBenzaldehydeAtomic layer depositionPhenolta216ta115ta114aromatic compoundsmonofunctional aromaticstemperature0104 chemical sciencesozonechemistryALDatomic layer depositionMLDLangmuir
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Low-temperature Molecular Layer Deposition Using Monofunctional Aromatic Precursors and Ozone-based Ring Opening Reactions

2017

Molecular layer deposition (MLD) is an increasingly used deposition technique for producing thin coatings consisting of purely organic or hybrid inorganic–organic materials. When organic materials are prepared, low deposition temperatures are often required to avoid decomposition, thus causing problems with low vapor pressure precursors. Monofunctional compounds have higher vapor pressures than traditional bi- or trifunctional MLD precursors, but do not offer the required functional groups for continuing the MLD growth in subsequent deposition cycles. In this study, we have used high vapor pressure monofunctional aromatic precursors in combination with ozone-triggered ring-opening reactions…

ring opening reactionhybrid organic-inorganicALDMLDmonofunctional aromaticslow-temperaturemechanism
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